Technique - (5) ENDOR (Electron Nuclear Double Resonance)

Type: Experimental

Description: Double-resonance EPR technique for resolving hyperfine couplings between electron and nuclear spins in molecular qubits and spin defect systems.

Department(s)/lab(s): Chemistry – Photon Science Institute / National EPR Facility | Bowen Group (Molecular Spin Qubits and EPR) @ Manchester
Summary:

Bowen leads the CQSE 'Spins and Qubits' theme at Manchester, focusing on organometallic molecular spin qubits for quantum sensing and computing. Research directions: (1) Organometallic La(II) and other rare-earth molecular qudits — designing molecules with multiple accessible spin states (qudits) for encoding quantum information and sensing; (2) Pulsed EPR characterization — Hahn echo, ESEEM, ENDOR at X/W/Q-band to measure coherence times and hyperfine couplings; (3) Integration of molecular qubits into devices — surface deposition and nanoscale addressing; (4) Multi-spin sensing — using exchange-coupled spin pairs as differential sensors of magnetic field gradients. Closely collaborates with Tuna and Winpenny.

Department(s)/lab(s): Chemistry | Freedman Group @ MIT
Summary:

PREFERRED. Freedman uses synthetic inorganic chemistry to design molecular qubits from the electron spin of paramagnetic coordination complexes (e.g. chromium-centered complexes), giving Angstrom-scale, chemically tunable control over qubit placement and coherence for quantum sensing, communication, and metrology applications, including collaborations targeting dark-matter detection and biological/materials sensing; she directs the Institute-wide Quantum@MIT initiative.

Department(s)/lab(s): Chemistry | Hoffman ENDOR Spectroscopy Group @ Northwestern
Summary:

Hoffman develops and applies electron-nuclear double resonance (ENDOR) spectroscopy -- a combination of EPR and NMR -- to resolve individual hyperfine-coupled nuclei at metalloenzyme active sites with atomic-scale precision, work that has revealed mechanisms of nitrogenase nitrogen fixation, radical-SAM enzyme catalysis, and copper/methane monooxygenase chemistry. The technique pushes magnetic-resonance spectroscopic resolution well past what conventional EPR can resolve, in a manner methodologically continuous with molecular spin-qubit sensing.

Department(s)/lab(s): Chemistry | Roessler EPR Spectroscopy Group @ Imperial
Summary:

Roessler uses continuous-wave and pulsed EPR/ENDOR spectroscopy to probe paramagnetic metal centres and radical intermediates in catalytic and bioinorganic systems, work that overlaps with the use of molecular spin centres as candidate EPR-addressable qubits/sensors.

Department(s)/lab(s): Chemistry – Photon Science Institute | Winpenny Group (Molecular Magnetism) @ Manchester
Summary:

Winpenny holds the Regius Chair in Chemistry at Manchester and is a world leader in molecular magnetism and molecular nanomagnets for quantum technologies. Research directions: (1) Molecular nanomagnets — synthesis of Cr7Ni 'horseshoe' rings and related cage clusters as prototype molecular qubits with long T2 times; (2) Multi-qubit molecular architectures — covalently linked molecular qubit pairs and arrays for quantum gate operations and distributed sensing; (3) Quantum error correction in molecules — designing molecular systems encoding logical qubits with error protection; (4) Quantum sensing applications — molecular spin systems as ultra-sensitive nanoscale magnetic sensors in the sub-nm regime. Leading the NPL M4Q Network and UK molecular qubit community.