Technique - (2) Vibrational and electronic strong coupling in optical microcavities

Type: Experimental

Description: Fabry-Perot and plasmonic cavities hybridised with molecular transitions to modify chemistry and generate polaritonic states.

Department(s)/lab(s): School of Chemistry | Hutchison Molecular Polaritonics Group @ UMelb
Summary:

Hutchison works on molecular polaritonics: what happens to chemistry when molecular electronic or vibrational transitions are strongly coupled to a confined optical mode in a Fabry-Perot or plasmonic nanocavity. He was among the first to show that vibrational strong coupling modifies ground-state chemical reactivity, and the group continues to probe polariton-modified energy transfer, photochemistry and transport, alongside single-molecule spectroscopy and 2D-material photonics. Positioned against the established body of NV-ensemble quantum sensing work — DEER, nanoscale NMR and T1 relaxometry protocols operating at pT/sqrt(Hz) field sensitivity — the connection to quantum sensing is the cavity: the same Purcell and collective-coupling physics that concentrates optical density of states around a molecule is what is used to improve photon collection and readout fidelity in NV ensembles operating at pT/sqrt(Hz). This is fundamental light-matter physics with a clear nonclassical-state angle.

Department(s)/lab(s): School of Chemistry | Molecular Photophysics Group (Lakhwani) @ USyd
Summary:

Lakhwani runs the Molecular Photophysics Group and is a chief investigator in ARC Exciton Science. The group works on strong light-matter coupling in organic semiconductors: forming exciton-polaritons in microcavities, driving them toward polariton lasing and condensation with electrically injected devices, and engineering host-guest energy funnelling to lower thresholds. A second thread is chiroptical spectroscopy — circular dichroism and circularly polarised luminescence of chiral organic films — which is a polarisation-resolved measurement of a very small differential signal. Positioned against the established body of NV-ensemble quantum sensing work — DEER, nanoscale NMR and T1 relaxometry protocols operating at pT/sqrt(Hz) field sensitivity — polaritonic quantum matter is a distinct route to non-classical states of light at room temperature, in contrast to the cryogenic or spin-based platforms that dominate pT/sqrt(Hz)-class sensing; the differential chiroptical measurements the group performs are, methodologically, small-signal detection problems of exactly the same type.