Grange leads the Optical Nanomaterial Group at ETH, developing nonlinear materials for quantum photonic integrated circuits. Research directions: (1) Barium titanate (BTO) nanophotonics — scalable CMOS-compatible BTO thin-film integrated circuits exploiting large χ(2) nonlinearity for quantum entangled photon-pair generation via SPDC; (2) Lithium niobate on insulator (LNOI) — quantum photonic integrated circuits for heralded single-photon sources and electro-optic transduction; (3) Second-harmonic generation sensing — SHG-active nanocrystals as contrast agents and phase-sensitive probes in biological imaging; (4) On-chip entangled photon sources for quantum communication and sensing. Strong quantum sensing application in nonlinear optical readout of quantum states.
Mulvaney directs the ARC Centre of Excellence in Exciton Science and runs Melbourne's nanoscience laboratory. The group's distinctive capability is single-particle and single-emitter optical spectroscopy: photon-antibunching and blinking statistics from individual quantum dots and perovskite nanocrystals, photothermal and dark-field spectroscopy of individual metal nanoparticles, and the electrochemical control of single-nanocrystal charge state. Applications run from LEDs and solar cells to quantum-dot probes for single-particle tracking in cells. Positioned against the established body of NV-ensemble quantum sensing work — DEER, nanoscale NMR and T1 relaxometry protocols operating at pT/sqrt(Hz) field sensitivity — his single-emitter photon-statistics measurements share the shot-noise-limited photon-counting methodology of NV-ensemble ODMR readout, and the group's nanocrystal probes are direct competitors/complements to nanodiamond in cellular sensing. Large, well-resourced group.